LOS ANGELES, Ca., May 22 (TOTI) --

Angelina Jolie is not happy about Brad Pitt and his relationship with ex-wife Jennifer Aniston. For years it wasn't an issue as Pitt and Aniston barely spoke. Now, however, the couple has been exchanging text messages and developing an ever more intimate personal relationship. Jolie, who confidently stole Pitt from Aniston in the first place, is not about to let her bitter rival back into the picture.

Now the drama is hitting a high note as Angelina Jolie has caught Brad Pitt in the act of chatting up Jen Aniston.

Early this month Brad was sitting in the kitchen of the Long Island mansion he shares with Jolie and their six children. He must have thought he was alone, because the six kids were all sleeping and Angelina was filming Salt. Pitt felt comfortable enough to phone Aniston. Unfortunately for him, Jolie came home early from filming and busted him!

"She heard him say, 'Relax, Jen. Everything will be OK,'" a family insider told Star. "Angie totally flipped out! She slammed her hand on the counter and stormed out of the room."

Brad was shocked. He quickly hung up and chased after Angelina. But it was too late to console her.

"She told Brad right then and there,'It's her or me!' Brad shot back, 'You talk to your exes - why can't I? She's just a friend and needed some advice.' But Angie didn't care. She told Brad, 'Enough with Jennifer!'"

Angelina has been finding more evidence of Pitt's growing relationship with Aniston and she's hitting the roof over it.

"He's been contacting Jen a lot lately, despite Angelina's jealousy," said the source. "They had several late-night conversations, and Brad enjoys their long chats, especially after he's been drinking. Jennifer takes his calls and listens attentively to his problems. She still cares about him and told him she always will."

Is Brad crazy? Why would he carelessly call Aniston from the house he shares with Jolie? What do you think will happen next?

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